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Question

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R:

Assertion A: During the boiling of water having a temporary hardness, Mg(HCO3)2 is converted to MgCO3.

Reason R: The solubility product of Mg(OH)2 is greater than that of MgCO3.

In the light of the above statements, choose the most appropriate answer from the options given below.

A
A is false but R is true
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B
Both A and R are true and R is the correct explanation of A
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C
Both A and R are true but R is NOT the correct explanation of A
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D
A is true but R is false
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Solution

The correct option is A A is false but R is true
Answer: (a)

Temporary hardness of water is due to the presence of bicarbonates of calcium and magnesium.
Temporary hardness is removed by boiling the water.

During heating, magnesium bicarbonate is converted to magnesium hydroxide.

Mg(HCO3)2Mg(OH)2+CO2

Calcium bicarbonate is converted to calcium carbonate.

Ca(HCO3)2CaCO3+CO2+H2O


Ksp Mg(OH)2<Ksp MgCO3

Hence, Mg(OH)2 precipitates first.


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