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Question

Given below are two statements:
Statement I: Frenkel defects are vacancy as well as interstitial defects.
Statement II: Frenkel defect leads to colour in ionic solids due to presence of F-centres.
Choose the most appropriate answer for the statements from the options given below:
(JEE Main 2021)

A
Both Statement I and Statement II are false
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B
Both Statement I and Statement II are true
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C
Statement I is false but Statement II is true
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D
Statement I is true but Statement II is false
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Solution

The correct option is D Statement I is true but Statement II is false
Frenkel defect: This defect is shown by ionic solids. The smaller ion (usually cation) is dislocated from its normal site to an interstitial site.

It creates a vacancy defect at its original site and an interstitial defect at its new location.

F-centre is formed in metal excess defect which is a non-stoichiometric defect.

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