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Question

Given below are two statements:
Statement I: o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding.
Statement II: o-Nitrophenol has high melting point due to hydrogen bonding.
In the light of the above statements, choose
the most appropriate answer from the
options given below:

A
Both statement I and statement II are true
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B
Statement I is false but statement II is true
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C
Statement I is true but statement II is false
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D
Both statement I and statement II are false
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Solution

The correct option is C Statement I is true but statement II is false
It has intramolecular hydrogen bonding and steam volatile.
  • Melting point is not effected by intramolecular hydrogen bonding but boiling point of a molecule decreases on intramolecular hydrogen bonding.
Hence, statement I is true, but statement II is false.

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