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Question

Given below is a list of compounds:
A) HCHO

B) CH3COCH3
C) PhCOCH3
D) PhCOPh
The increasing order of the rate of HCN addition to compounds, A,B,C and D is :

A
A<B<C<D
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B
D<B<C<A
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C
D<C<B<A
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D
C<D<B<A
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Solution

The correct option is B D<C<B<A
In general, aldehydes are more reactive than ketones.
Among ketones, the one with more phenyl group will be more stabilized and hence, will be less reactive.
Therefore, the correct order of stability is D<C<B<A.

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