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Standard XII
Chemistry
Stoichiometric Calculations
Given, Cs +...
Question
Given,
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Δ
H
=
+
94.2
k
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
+
68.3
Δ
H
=
k
c
a
l
C
H
4
(
g
)
+
2
O
2
(
g
)
→
C
O
2
(
g
)
+
2
H
2
O
(
l
)
Δ
H
=
+
210.8
k
c
a
l
The heat of formation of methane in
k
c
a
l
will be:
A
45.9
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B
47.8
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C
20.2
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D
47.3
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Solution
The correct option is
C
20.2
The thermochemical reactions are as given below.
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Δ
H
=
+
94.2
k
c
a
l
-----------(1)
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
Δ
H
=
+
68.3
k
c
a
l
----------(2)
C
H
4
(
g
)
+
2
O
2
(
g
)
→
C
O
2
(
g
)
+
2
H
2
O
(
l
)
Δ
H
=
+
210.8
k
c
a
l
--------------(3)
C
(
s
)
+
H
2
(
g
)
→
C
H
4
(
g
)
The equation (2) is multiplied by two and equation (3) is reversed. They are then added to the equation (1).
Hence, the heat of formation of methane is
94.2
+
2
(
68.3
)
−
210.8
=
+
20.2
kcal
Suggest Corrections
0
Similar questions
Q.
Given
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
+
94.2
K
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
+
68.3
K
c
a
l
C
H
4
(
g
)
+
2
O
2
(
g
)
→
C
O
2
(
g
)
+
2
H
2
O
(
l
)
+
210.8
K
c
a
l
The heat of formation of methane in kcal will be:
Q.
Given,
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Δ
H
=
−
94.2
k
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
Δ
H
=
−
68.3
k
c
a
l
C
H
4
(
g
)
+
2
O
2
(
g
)
→
C
O
2
(
g
)
+
2
H
2
O
(
l
)
Δ
H
=
−
210.8
k
c
a
l
The heat of formation of methane in kcal will be :
Q.
Calculate the heat of formation of
C
H
3
C
O
O
H
(
l
)
at
25
∘
C
from the following data;
C
H
3
C
O
O
H
(
l
)
+
2
O
2
(
g
)
→
2
C
O
2
+
2
H
2
O
(
l
)
;
Δ
H
=
−
208.34
kcal
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
94.05
kcal
H
2
(
g
)
+
1
2
O
2
→
H
2
O
(
l
)
;
Δ
H
=
−
68.32
kcal
Q.
Using the following thermochemical data,
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Δ
H
=
−
94.0
k
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
Δ
H
=
−
68.0
k
c
a
l
C
H
3
C
O
O
H
(
l
)
+
2
O
2
(
g
)
→
2
C
O
2
(
g
)
+
2
H
2
O
(
l
)
Δ
H
=
−
210.0
k
c
a
l
the heat of formation of acetic acaid is :
Q.
From the following data of heats of combustion, find the heat of formation of
C
H
3
O
H
(
l
)
C
H
3
O
H
(
l
)
+
3
2
O
2
(
g
)
→
C
O
2
(
g
)
+
2
H
2
O
(
l
)
;
△
r
H
⊖
=
−
726
k
J
C
(
s
)
+
O
2
(
g
)
→
C
O
2
(
g
)
,
Δ
H
=
−
394
k
J
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
,
Δ
H
=
−
286
k
J
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