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Question

Given:From the following compound(s), which on reaction with HNO3 will give the product having degree of rotation, [α]D=52.7 is/are:

A
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B
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C
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D
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Solution

The correct option is D

Since, we have to get the product (x) of [α]D=52.7 i.e. the enantiomer of product (P) which is only possible from (c) & (d).
From (c), enantiomer of saccharic acid is obtained.
From (d), enantiomer of saccharic acid is obtained.

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