Given, standard electrode potentials, Fe2++2e−→Fe,Eo=−0.440V Fe3++3e−→Fe,Eo=−0.036V
The standard electrode potential (Eo) for Fe3++e−→Fe2+ is:
A
+0.771V
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B
−0.771V
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C
+0.404V
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D
−0.417V
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Solution
The correct option is D+0.404V Fe2++2e−→Fe,Eo=−0.440 ......(1)
Fe3++3e−→Fe,Eo=−0.036.......(2)
The standard electrode potential for Fe3++e−→Fe2+ is obtained by substracting the value of the standard electrode potential for first reaction from the standard electrode potential for second reaction. −0.036−(−0.440)=0.404V