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Question

Given that, ΔTf is the depression in freezing point of the solvent in a solution of a non-volatile non-electrolytic solute of molality m, then quantity - limm0(ΔTf/m) is ___ (equal\different) to molal depression constant.

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Solution

The molal freezing point depression constant is the depression in freezing point for 1 molal solution.
ΔTf=Kf×m
When,
m=1, ΔTf=Kf

Thus, when ΔTf is the depression in freezing point of the solvent in a solution of a non-volatile solute of molality m, then quantity.
limm0(ΔTf/m) is equal to molal depression constant.

So, the correct answer is equal.

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