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Question

Given that EoFe2+|Fe=0.44V;EoFe2+|Fe3+=0.77V
If Fe2+,Fe3+ and Fe solid are kept together, then:

A
Fe3+ increases
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B
Fe3+ decreases
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C
Fe2+,Fe3+ remain unchanged
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D
Fe2+ decreases
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Solution

The correct option is B Fe3+ decreases
Cell reaction : 2Fe3++Fe3Fe2+
Ecell=0.77(0.44)=1.21V=+ve so
Fe3+ and Fe will reduce.

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