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Question

Given that:
(i) C (graphite)+O2(g)CO2(g); ΔrHo=x kJmol1.
(ii) C (graphite)+12O2(g)CO(g); ΔrHo=y kJmol1
(iii) CO(g)+12O2(g)CO2(g); ΔrHo=z kJmol1

Based on the given thermochemical equations, find out which one of the following algebraic relationships is correct?

A
z=x+y
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B
x=yz
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C
x=y+z
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D
y=2zx
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Solution

The correct option is B x=y+z
C(graphite)+O2(g)CO2(g)ΔrHo=xkJ/mol .(1)
C(graphite)+12O2(g)CO(g)ΔrHo=ykJ/mol ..(2)
CO(g)+12O2(g)CO2(g)ΔrHo=zkJ/mol .(3)
Now,
(1)=(2)+(3)
x=y+z.

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