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Question

Given the standard electrode potentials,

K+K=2.93 V,

Ag+Ag=0.80 V

Hg2+Hg=0.79V,

Mg2+Mg=2.37 V

Cr3+Cr=0.74 V

Arrange these metals in their increasing order of reducing power.

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Solution

Metal which has lower reduction potential (more negative E value) has greater reducing capacity because it itself gets oxidised more easily.

MetalsReduction,Potentials(volts)Ag<Hg<Cr<Mg<K−−−−−−−−−−−−−−−−−−Reducing power increases0.80>0.79>0.74>2.37>2.93−−−−−−−−−−−−−−−−−−Reducing power increases

The lower the reduction potential, the higher is the reducing power. The given standard
electrode potentials increase in the order of

K+K < Mg2+Mg < Cr3+Cr < Hg2+Hg < Ag+Ag
Hence, the reducing power of the given metals increases in the following order:

Ag < Hg < Cr < Mg < K


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