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Question

Given the standard potential of the following at 25C. MnO2Mn3+; E=0.95V
Mn3+Mn2+; E=1.51V
The standard potential of MnO2Mn2+ is:

A
0.56V
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B
2.46V
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C
1.23V
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D
1.23V
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Solution

The correct option is C 1.23V
2e+MnO2Mn2+; E = ?
ΔG=2FE
i. e+MnO2Mn3+; ΔG1=FE=0.95F
ii. e+Mn3+Mn3+; ΔG2=FE=1.51E
Equations (i) + (ii) give the desired equation.
2FE=(0.951.51)F
E=1.23V

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