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Oxidation of Alcohols

Given the str...

Question

Given the structures of products A, B and C in the following reactions:
(i) $C H_{3} C H_{2} B r K C N - -- \to A L i A l H_{4} - --- \to B H N O_{2} - --- \to 0^{\circ} C C$
(ii) $C H_{3} C O O H N H_{3} - -- \to Δ A N a O H + B r_{2} - ------ \to B C H C l_{3} + A l c . K O H - ---------- \to C$

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Solution

(i) $C H_{3} C H_{2} B r K C N - -- \to C H_{3} C H_{2} C N L i A l H_{3} - --- \to C H_{3} C H_{2} C H_{2} N H_{2} H N O_{2} - --- \to C H_{3} C H_{2} C H_{2} O H$
(ii) $C H_{3} C O O H N H_{3} - -- \to C H_{3} C O N H_{2} N a O H + B r_{2} - ------ \to C H_{3} N H_{2} C H C l_{3} + A l c . K O H - ---------- \to C H_{3} N C$

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Similar questions

Q. Give the structures of

A, B

C

in the following reactions:
(i)

C H_{3} B r K C N - ------ \to A L i A l H_{4} - ------- \to B H N O_{2} - ------- \to 273 K C

C H_{3} C O O H N H_{3} - ------ \to Δ A {B r}_{2} + K O H - --------- \to B C H {C l}_{3} + N a O H - ------------ \to C

Q. Complete the following reactions:
(i)

C H_{3} C O O H N H_{3} - -- \to Δ (A) B r_{2} / K O H - ----- \to (B) H N O_{2} - --- \to (C)

C H_{3} N H_{2} (A) - - \to C H_{3} O H (B) - - \to C H_{3} I

Q. Give the structures of products

A, B a n d C

in the following reactions:
(i)

C H_{3} C H_{2} B r K C N ⟶ A L i A l H_{4} ⟶ B H N O_{2} - --- \to 0^{o} C C

C H_{3} C O O H N H_{3} - -- \to Δ A N a O H + B r_{2} ⟶ B C H C L_{3} + A l c . K O H ⟶ C

Give the structures of A, B and C in the following reactions:

(i)

(ii)

(iii)

(iv)

(v)

(vi)

Q. Predict the products of the following reactions:
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\begin{matrix} C H_{3} - & C & = 0 H C N - ----------- \to ? | {C H}_{3} \end{matrix}

C_{6} H_{5} - C H_{2} - C H_{3} (a) K M n O_{4} / K O H ⟶ (b) H^{+} ?

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