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Question

Graphite is soft solid lubricant extremely difficult to melt. The reason for this anomalous behavior is that graphite:

A
has molecules of variable molecular masses like polymers
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B
has carbon atoms arranged in large plates of rings of strongly bound carbon atoms with weak interpolate bonds
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C
is a non-crystalline substance
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D
is an allotropic form of diamond
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Solution

The correct option is B has carbon atoms arranged in large plates of rings of strongly bound carbon atoms with weak interpolate bonds



In graphite, carbon is sp2 hybridized and each carbon is thus linked to three other carbon atoms forming hexagonal rings. Since only three electrons of each carbon are used in making a hexagonal ring, the fourth electron of each carbon is free to move and is thus delocalized ober the ring. This makes graphite good conductors of electricity.

Also, graphite has a two-dimensional shell-like structure. Such sheets are held together by weak van der Waals forces; it is because of these weak forces of attraction, one layer can slip over the other thus graphite acts as an exceptional lubricant.


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