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Potassium Permanganate

Guys is this ...

Question

Guys is this statement right that Intramolecular hydrogen bonding decreases the acidic strength while intermolecular hydrogen bonding increases the acidic strength??

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Solution

Yes, ortho nitrophenol is less acidic due to stabilization by intramolecular hydrogen bonding.

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Q. Ice float on water. Which hydrogen bond is responsible for this? Intermolecular hydrogen bond or intramolecular hydrogen bond.

Q. Ortho-nitrophenol is steam volatile whereas para-nitrophenol is not. This is due to

1.

Intramolecular hydrogen bonding present in ortho-nitrophenol

2.

Intermolecular hydrogen bonding present in para-nitrophenol

3.

Intramolecular hydrogen bonding present in para-nitrophenol

4.

Inter-molecular hydrogen bonding present in ortho-nitrophenol.

Q. Hydrogen bonding is of two types -

t

Intramolecular and intermolecular Am I right ?

Q. Bond strength of Hydrogen halides decreases in the order:

Q. Statement I: Acidic strength increases in the order given as

H F << H C l << H B r << H I

Statement II: As the size of the elements

F, C l, B r, I

increases down the group, the bond strength of

H F, H C l, H B r, and H I

decreases and so the acidic strength increases.

In the light of the above statements, choose the correct answer from the options given below.

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