The correct option is D -22 kcal
Given reaction is,
H2+Cl2→2HCl ΔH=−44 kcal
Heat of formation is the enthalpy change accompanying the formation of one mole of the compound from its constituent elements.
For 2 moles of HCl,ΔH=−44 kcal
For 1 mole of HCl, ΔH=−442=−22 kcal