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Question

H2(g)+12O2(g)H2O(l); ΔH=286.2kJ; H2O(l)H+(aq)+OH(aq);ΔH=+57.3kJ. Enthalpy of ionisation of OH in aqueous solution is:

A
228.5kJ
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B
+228.5kJ
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C
343.5kJ
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D
zero
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Solution

The correct option is A 228.5kJ
Solution:- (A) 228.5kJ
Given:-
H2(g)+O2(g)H2O(l);ΔH=286.2kJ.....(1)
H2O(l)H+(aq.)+OH(aq.);ΔH=+57.3kJ.....(2)
Adding eqn(1)&(2), we have
H2(g)+O2(g)+H2O(l)H2O(l)+H+(aq.)+OH(aq.);ΔH=[57.3+(286.2)]kJ
H2(g)+O2(g)H+(aq.)+OH(aq.);ΔH=228.9kJ228.5kJ
Hence the enthalpy of ionisation of OH in aqeuous solution is 228.5kJ.

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