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Question

H2O2 is always stored in black bottles because:

A
it is highly unstable
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B
it has high enthalpy of decomposition
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C
it undergoes auto oxidation on prolonged standing
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D
none of the above
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Solution

The correct option is C it undergoes auto oxidation on prolonged standing
On prolonged standing, hydrogen peroxide undergoes auto oxidation or disproportionation as follows:

2H2O22H2O+O2

Hence, hydrogen peroxide is always stored in black bottles, which cuts off the light and suppresses the auto-oxidation.

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