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Question

H2 reacts much faster with Cl2 then D2, because:

A
rate of diffusion of H2 is greater than D2
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B
H2 has lower energy of activation than D2
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C
both (A) and (B) are correct
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D
none of the above is correct
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Solution

The correct option is B H2 has lower energy of activation than D2
H2 reacts much faster with Cl2 than D2, because H2 has lower energy of activation than D2. This slowing of the reaction with the heavier isotope is called the deuterium isotope effect.

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