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H2O2 has lower boiling point than water.
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H2O2 has very high boiling point than water.
The boiling point of H2O2 is 150.2oC, approximately 50 degrees higher than water; H2O2 exhibits hydrogen bonding and with one additional oxygen atom, compared to H2O, there are more sites available to form hydrogen bonds. With potentially more hydrogen bonding in H2O2, the boiling point will be greater.

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