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Question

H2S acts only as a reducing agent while SO2 can act both as a reducing and oxidizing agent because


A

S in H2S has - 2 oxidation state

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B

S in SO2 has oxidation state + 4

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C

Hydrogen in H2S more +ve than oxygen

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D

Oxygen is more - ve in SO2

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Solution

The correct option is B

S in SO2 has oxidation state + 4


In H2S, Sulphur atom exhibits (-2) oxidation state, which is the least for the pnictogen.
As for its highest oxidation state - Sulphur exhibits (+6) in H2SO4.
In SO2, sulphur exhibits a (+4) oxidation state, which is in between the extremes.
Hence SO2 shows both oxidising and reducing properties.


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