The correct option is A 1∘, 2∘, 3∘, 4∘ and 1∘, 2∘, 3∘
All proteins have primary, secondary and tertiary structures but quaternary structures only arise when a protein is made up of two or more polypeptide chains.
Hemoglobin is the oxygen-transporting protein of red blood cells and is a globular protein with a quaternary structure. Hemoglobin consists of four polypeptide subunits; 2 alpha chains and two beta chains.
Unlike haemoglobin, myoglobin does not have a quaternary structure, as it consists of a single polypeptide chain.