The correct option is B NaHCO3
Both HCHO and HCOOH react with AgNO3/NH4OH
CuSO4/NaOH solution. But HCOOH gives effervescences of CO2 when reacts with NaHCO3, whereas HCHO does not give any effervescence of CO2 when reacts with NaHCO3.
HCOOH+NaHCO3⟶HCOONa+H2O+CO2↑