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Question

HCl is prepared by heating NaCl with conc.H2SO4. But HI cannot be prepared by treating NaI with conc.H2SO4. Identify the reason.

A
H2SO4 is oxidised by HI and not oxidised by HCl
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B
HI is oxidised by H2SO4 and HCl is not oxidised by HI
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C
HI dissociates on treatment with H2SO4 and HCl does not dissociate
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D
Reaction of H2SO4 with HI is reversible whereas with HCl is irreversible
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Solution

The correct option is B HI is oxidised by H2SO4 and HCl is not oxidised by HI

HCl is prepared by heating NaCl with conc.H2SO4. But HI cannot be prepared by treating NaI with conc.H2SO4. Because HI is oxidised by H2SO4 and HCl is not oxidised by HI.

Hence, option B is correct.


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