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Question

Heat is supplied to a diatomic gas at a constant pressure. The ratio of ΔQ:ΔU:ΔW is

A
5:3:2
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B
5:2:3
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C
7:5:2
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D
7:2:5
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Solution

The correct option is C 7:5:2
From first law of thermodynamics,
ΔQ=ΔU+ΔW
As the process is isobaric, we can modify it as
ΔQ=ΔU+μRΔT
[W=PΔV=μRΔT]

Gas is ideal and diatomic in nature.
Change in internal energy
ΔU=μCVΔT=52μRΔT [CV=52R]
ΔU=52ΔW .......(1)

Thus, heat supplied at a constant pressure, can be written as
ΔQ=μCPΔT
ΔQ=72μRΔT
[CP=72R]
ΔQ=72ΔW ......(2)

From (1) and (2), we get
ΔQ:ΔU:ΔW=7:5:2
Hence, option (c) is the correct answer.

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