Heat of formation of 2 moles of NH3(g) is −90kJ; bond energies of H−H andN−N bonds are 435kJ and 390kJmol−1 respectively. The value of the bond energy of N≡N will be:
A
−472.5kJ
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B
−945kJ
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C
472.5kJ
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D
945kJmol−1
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Solution
The correct option is D945kJmol−1 ΔHreaction=∑(BE)reactants−∑(BE)products −90=x+3×435−6×390 x=945kJmol−1