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Question

Heat of neutralization of HCl and NaOH is x kJ and that of CH3COOH and NaOH is y kJ. What is heat of ionization of CH3COOH.

A
(xy) kJ
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B
(yx) kJ
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C
(x+y) kJ
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D
(x+y) kJ
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Solution

The correct option is B (yx) kJ
i)HCL+NaOHNaCl+H2O ; Δ H=xKJ
ii)CH3COOH+NaOHCH3COONa+H2O;ΔH=yKJ
Reversing (i) and adding (ii) gives,
NaCl+CH3COOHCH3COONa+HCl;ΔH(yx)KJ
(iii)CH3COOHCH3COO+H+;ΔH(yx)KJ
The equation (iii) gives the heat of ionization of CH3COOH

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