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Question

Heat of reaction for C6H12O6(s) + 6O2 6CO2(g) + 6H2O(v) at constant pressure is 651 K cal at 17 C. What is the heat of reaction at constant volume at 17 C?


A

-654.48 Kcal

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B

-655.48 Kcal

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C

-653.48 Kcal

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D

None of these

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Solution

The correct option is A

-654.48 Kcal


We know that Δ H = Δ U + Δ nRT

Given Δ H = 651 × 103cal; R = 2 calorie

T = 290K; Δ n = 6 + 6 6 = 6

651 × 103 = Δ U + 6 × 2 × 290

Δ U = 654.48 kcal


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