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Byju's Answer
Standard XII
Chemistry
Hess' Law
Heat of react...
Question
Heat of reaction for the reaction is:
P
C
l
5
(
g
)
+
H
2
O
(
g
)
⟶
P
O
C
l
3
(
g
)
+
2
H
C
l
(
g
)
Given that,
P
w
h
i
t
e
+
(
3
/
2
)
C
l
2
(
g
)
+
1
2
O
2
(
g
)
⟶
P
O
C
l
3
;
Δ
H
=
−
135.5
k
c
a
l
H
2
(
g
)
+
C
l
2
(
g
)
⟶
+
2
H
C
l
(
g
)
;
Δ
H
=
−
44.1
k
c
a
l
P
(
w
)
+
(
5
/
2
)
C
l
2
(
g
)
⟶
P
C
l
5
(
g
)
;
Δ
H
=
−
89.6
k
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
⟶
H
2
O
(
g
)
;
Δ
H
=
−
57.8
k
c
a
l
A
−
32.2
k
c
a
l
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B
−
52.5
k
c
a
l
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C
−
45.2
k
c
a
l
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D
None of these
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Solution
The correct option is
A
−
32.2
k
c
a
l
P
w
h
i
t
e
+
3
2
C
l
2
(
g
)
+
1
2
O
2
(
g
)
⟶
P
O
C
l
3
;
Δ
H
1
=
−
135.5
k
c
a
l
H
2
(
g
)
+
C
l
2
(
g
)
⟶
+
2
H
C
l
(
g
)
;
Δ
H
2
=
−
44.1
k
c
a
l
P
(
w
)
+
5
2
C
l
2
(
g
)
⟶
P
C
l
5
(
g
)
;
Δ
H
3
=
−
89.6
k
c
a
l
H
2
(
g
)
+
1
2
O
2
(
g
)
⟶
H
2
O
(
g
)
;
Δ
H
4
=
−
57.8
k
c
a
l
The final reaction is obtained by reversing 3 and 4 and adding 1 and 2 to it:
P
C
l
5
(
g
)
+
H
2
O
(
g
)
⟶
P
O
C
l
3
(
g
)
+
2
H
C
l
(
g
)
Δ
H
=
Δ
H
1
+
Δ
H
2
−
Δ
H
3
−
Δ
H
4
.
⟹
Δ
H
=
−
135.5
−
44.1
+
89.6
+
57.8
=
−
32.2
k
c
a
l
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0
Similar questions
Q.
If,
H
2
(
g
)
+
C
l
2
(
g
)
→
2
H
C
l
(
g
)
;
Δ
H
=
−
44
K
c
a
l
2
N
a
(
s
)
+
2
H
C
l
(
g
)
→
2
N
a
C
l
(
s
)
+
H
2
(
g
)
;
Δ
H
=
−
152
K
c
a
l
then,
N
a
(
s
)
+
1
2
C
l
2
(
g
)
→
N
a
C
l
(
s
)
;
Δ
H
=
?
Q.
Calculate
Δ
H
in
k
J
for the following reaction:
C
(
g
)
+
O
2
(
g
)
→
C
O
2
(
g
)
Given that,
H
2
O
(
g
)
+
C
(
g
)
→
C
O
(
g
)
+
H
2
(
g
)
;
Δ
H
=
+
131
k
J
C
O
(
g
)
+
1
2
O
2
(
g
)
→
C
O
2
(
g
)
;
Δ
H
=
−
282
k
J
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
g
)
;
Δ
H
=
−
242
k
J
Q.
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
g
)
;
Δ
H
=
x
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
;
Δ
H
=
y
Heat of vaporisation of water is:
Q.
2
B
(
s
)
+
3
2
O
_
2
(
g
)
→
B
2
O
3
(
s
.
)
Δ
H
=
−
1273
k
j
H
_
2
(
g
)
+
1
2
O
_
2
(
g
)
→
H
_
2
O
(
l
)
Δ
H
=
−
286
k
j
H
2
O
(
l
)
→
H
2
O
(
g
)
Δ
H
=
44
k
j
2
B
(
s
)
+
3
H
2
(
g
)
→
B
2
H
6
(
g
)
Δ
H
=
365
k
j
B
2
H
6
(
g
)
+
3
O
2
(
g
)
B
2
O
3
(
s
)
+
3
H
2
O
(
g
)
Δ
H
=
?
Q.
The enthalpy of vapourisation of liquid water using the data
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
l
)
;
Δ
H
=
−
285.77
K
J
m
o
l
−
1
H
2
(
g
)
+
1
2
O
2
(
g
)
→
H
2
O
(
g
)
;
Δ
H
=
−
241.84
K
J
m
o
l
−
1
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