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Stoichiometry

Heating chlor...

Question

Heating chloroethane with _________ yields a product containing isocyanide group.

A

A g C N

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B

K C N

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C

H C N

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D

H N O_{3}

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Solution

The correct option is B $A g C N$
Ethyl chloride reacts with $K C N / N a C N$ and alkyl cyanide forms but ethyl chloride reacts with $A g C N$ and isocyanide forms.

$C_{2} H_{5} C l + A g C N ⟶ C_{2} H_{5} N C + A g C l$

Option A is correct.

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Similar questions

Q. Assertion :Treatment of chloroethane with a saturated solution of

A g C N

gives ethyl isocyanide as the major product. Reason: Cyanide

(C N^{-})

is an ambident nucleophile.

Q. Given below are two statements labelled as Assertion (A) and Reason (R).
Assertion (A): Treatment of chloroethane with a saturated solution of

A g C N

gives ethyl isocyanide as a major product.
Reason (R): Cyanide ion

(C N^{-})

is an ambident nucleophile.

Q. How will you convent (i) chloroethane to butane (ii) Methylamine to methyl isocyanide?

Q. Assertion: Ethyl chloride with ethanolic

A g C N

gives ethyl isocyanide as major product.
Reason: In ethyl cyanide, carbon of

C N

s p

Q. Hydrolysis of alkyl isocyanide yields :

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