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Byju's Answer
Standard XII
Chemistry
Ion Electron Method
HgO is analys...
Question
H
g
O
is analysed by reaction with iodine and then titrating with an acid. The equivalent mass of
H
g
O
is
:
H
2
O
+
H
g
O
+
4
I
−
→
H
g
I
2
−
4
+
2
O
H
−
A
M
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B
M
2
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C
M
4
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D
M
3
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Solution
The correct option is
D
M
2
H
2
O
+
H
g
O
+
4
I
−
→
H
g
I
2
−
4
+
2
O
H
−
In this reaction, one mole of
H
g
O
gives two moles of
O
H
−
ions, so Eq. wt. of
H
g
O
is
M
2
.
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0
Similar questions
Q.
Mercuric oxide,
H
g
O
, can be analysed by reaction with iodide and then titration with an acid.
H
g
O
+
4
I
−
⟶
H
g
I
2
−
4
+
2
O
H
−
then,
H
g
O
≡
2
O
H
−
≡
2
H
+
So, if
x
moles
H
g
O
requires
10
moles of a dibasic acid then what is the value
x
.
Q.
Consider this equilibrium, for which
Δ
H
<
0
.
H
g
O
(
s
)
+
4
I
−
(
a
q
.
)
+
H
2
O
(
l
)
⇌
H
g
I
4
2
−
+
2
O
H
−
Which changes will increase the equilibrium concentration
H
g
I
4
2
−
?
I
. Increasing the mass of
H
g
O
(
s
)
present
I
I
. Increasing
[
I
−
]
I
I
I
. Adding
1
M
H
C
l
Q.
Consider the equilibrium:
H
g
O
(
s
)
+
4
I
−
(
a
q
)
+
H
2
O
(
l
)
⇌
H
g
I
2
−
4
(
a
q
)
+
20
H
−
(
a
q
)
Which changes will decrease the equilibrium concentration of
H
g
I
2
−
4
?
Q.
Calculate the mass of mercury which can be liberated from
H
g
O
at
25
∘
C
by the treatment of excess
H
g
O
with
41.84
k
J
of heat at
(i) constant pressure (ii) constant volume conditions.
Given:
△
H
∘
f
(
H
g
O
,
s
)
=
−
90
k
J
m
o
l
−
1
and
M
(
H
g
)
=
200.6
g
m
o
l
−
1
.
Q.
In which of the following electrochemical cell overall cell reaction is :
H
g
O
(
s
)
+
H
2
(
g
)
→
H
g
(
ℓ
)
+
H
2
O
(
ℓ
)
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