Highest oxidation state of Mn is present in :
i. KmnnO4
1+n−4(2)=0
n=7
ii. K2nMnO4
2+n−4(2)=0
n=6
iii. Mnn2O3
2n−3(2)=0
n=3
So, oxidation state of Mn iss highest in KMnO4
When MnO2 is fused with KOH a coloured compound is formed. The product and its colour are
MnO2 when fused with KOH and oxidized in air gives a dark green compound X. In acidic X. In acidic solution, X undergoes disproportion to give an intense purple compound Y and MnO2. The compounds X and Y respectively, are