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Acidity of Alcohols and Phenols

HO-CH2-CH2- ...

Question

$H O - C H_{2} - C H_{2} - C | O H - C H_{2} - O H H I O_{4} - -- \to Δ$
Identify the product of the above reaction.

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Solution

$H I O_{4}$ is an good oxidizing agent, selectively oxidize, $1, 2 - d i o l s$ and form carbonyl compound.

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\begin{matrix} O | | C H_{3} - C H_{2} - & C & - C l + C H_{3} - O H / N a O C H_{3} ⟶ \end{matrix}

What is the product of above reaction?

H O - C H_{2} - C | H O H - C H_{2} - O H

IUPAC name of the given compound is :

Q. Identify the type of the following reaction of carbon compounds.
a. CH₃ -CH₂ -CH₂-OH → CH₃ -CH₂ -COOH
b. CH₃ -CH₂ -CH₃ → 3CO₂ + 4H₂O
c. CH₃ -CH = CH -CH₃ + Br₂ → CH₃ -CHBr - CHBr -CH₃
d. CH₃ -CH₃ + Cl₂→ CH₃ -CH₂ -Cl + HCl
e. CH₃-CH₂ -CH₂ -CH₂ -OH → CH₃ -CH₂ -CH=CH₂ + H₂O
f. CH₃-CH₂ -COOH + NaOH → CH₃ -CH₂ -COO - Na⁺ + H₂O
g. CH₃ -COOH + CH₃ -OH → CH₃ -COO- CH₃ + H₂O

Q. Write the IUPAC name of the given compound:

\begin{matrix} H O - C H_{2} - & C H & - C H_{2} - O H | C H_{3} \end{matrix}

P h - C H_{2} - C | H O H - C H_{3} K - \to C_{2} H_{5} B r - ---- \to (A)

(A)

in above reaction is :

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Acidity of Alcohols and Phenols

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