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Question

How can you prove that hydrochloric acid contains
(i) hydrogen,
(ii) chlorine?

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Solution

(i) When hydrochloric acid reacts with metals, it forms the respective chlorides, liberating hydrogen gas in the process.
Metal + Hydrochloric acid → Metal chloride + Hydrogen

For example, hydrochloric acid reacts with magnesium to form magnesium chloride and hydrogen gas.

Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
Magnesium Magnesium chloride Hydrogen

(ii) When hydrochloric acid reacts with strong oxidising agents, chlorine gas is liberated.

Oxidising agent + Conc. hydrochloric acid →​ Salt + Water + Chlorine

For example, concentrated hydrochloric acid reacts with manganese dioxide to form manganese chloride and chlorine gas.

MnO2(s) + 4HCl(aq) →​ MnCl2(aq) + 2H2O(l) + Cl2(g)
Manganese Manganese chloride Chlorine
dioxide
(black)


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