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Standard XII

Chemistry

Introduction to Alkenes

How do you co...

Question

How do you convert the following :
(i) Prop-1-ene to 1-fluoropropane
(ii) Chlorobenzene to 2-chlorotoluene
(iii) Ethanol to propanenitrile

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Solution

$(i) C H_{3} - C H = C H_{2} Proppene H B r, R O O R^{'} - ------- \to Peroxide effect C H_{3} - C H_{2} - C H_{2} B r 1-Bromopropane H g_{2} F_{2} - --- \to C H_{3} - C H_{2} - C H_{2} - F 1-Fluorpropane$

$(i i i) C H_{3} C H_{2} - O H Ethanol H B r - --- \to - H_{2} O C H_{3} C H_{2} B r Bromoethane A l c . K C N - ----- \to - K B r C H_{3} C H_{2} - C N Propanenitrile$

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How do you convert the following:

(i) Prop-1-ene to 1-fluoropropane

(ii) Chlorobenzene to 2-chlorotoluene

(iii) Ethanol to propanenitrile

What happens when

(i) n-butyl chloride is treated with alcoholic KOH?

(ii) 2, 4, 6-trinitrochlorobenzene is subjected to hydrolysis?

(iii) methyl chloride is treated with AgCN?

Q. How do you convert:
(i) Chlorobenzene to biphenyl
(ii) Propene to 1-iodopropane
(iii) 2-bromobutane to but-2-ene

Q. How the following conversions can be carried out?
(i) Propene to propan-1-ol (ii) Ethanol to but-1-yne
(iii) 1-Bromopropane to 2-bromopropane (iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene (vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile (viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane (x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid (xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol (xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol (xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane (xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide (xx) Aniline to phenylisocyanide

How the following conversions can be carried out?

(i) Propene to propan-1-ol

(ii) Ethanol to but-1-yne

(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol

(v) Benzene to 4-bromonitrobenzene

(vi) Benzyl alcohol to 2-phenylethanoic acid

(vii) Ethanol to propanenitrile

(viii) Aniline to chlorobenzene

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane

(xi) Ethyl chloride to propanoic acid

(xii) But-1-ene to n-butyliodide

(xiii) 2-Chloropropane to 1-propanol

(xiv) Isopropyl alcohol to iodoform

(xv) Chlorobenzene to p-nitrophenol

(xvi) 2-Bromopropane to 1-bromopropane

(xvii) Chloroethane to butane

(xviii) Benzene to diphenyl

(xix) tert-Butyl bromide to isobutyl bromide

(xx) Aniline to phenylisocyanide

How will you bring about the following conversions?

(i) Ethanol to but-1-yne

(ii) Ethane to bromoethene

(iii) Propene to 1-nitropropane

(iv) Toluene to benzyl alcohol

(v) Propene to propyne

(vi) Ethanol to ethyl fluoride

(vii) Bromomethane to propanone

(viii) But-1-ene to but-2-ene

(ix) 1-Chlorobutane to n-octane

(x) Benzene to biphenyl.

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How do you convert the following : (i) Prop-1-ene to 1-fluoropropane (ii) Chlorobenzene to 2-chlorotoluene (iii) Ethanol to propanenitrile

(i) CH3−CH=CH2ProppeneHBr,ROOR′−−−−−−−−→Peroxide effectCH3−CH2−CH2Br1-BromopropaneHg2F2−−−−→CH3−CH2−CH2−F1-Fluorpropane (iii) CH3CH2−OHEthanolHBr−−−−→−H2OCH3CH2BrBromoethaneAlc.KCN−−−−−−→−KBrCH3CH2−CNPropanenitrile

How do you convert the following :
(i) Prop-1-ene to 1-fluoropropane
(ii) Chlorobenzene to 2-chlorotoluene
(iii) Ethanol to propanenitrile