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Question

How does a substitution reaction differ from an addition reaction?


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Solution

Difference between substitution reaction and addition reaction

Substitution reactionAddition reaction
A substitution reaction is a reaction that involves the replacement of an atom or a group of atoms by another atom or a group of atoms. The addition reaction is the combination of two or more atoms or molecules in order to form a large molecule.
This results in a byproduct named the leaving group.Most addition reactions are limited to molecules with unsaturation that has either double bonds (=) or triple bonds ().

Example: Addition of Hydrogen to Ethene

C2H4(g)+H2(g)Ni/Pt250°CC2H6(g)EtheneEthane

Example: Reaction of Methane with Chlorine in presence of light

CH4(g)+Cl2(g)sunlightCH3Cl(g)+HCl(g)MethaneChloroHydrogenmethanechloride


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