:The conductivity of semiconductors is increased by adding an appropriate amount of suitable impurity or doping. Doping can be done with an impurity which is electron rich or electron deficient as compared to the intrinsic semiconductor, silicon or germanium. Such impurities introduce electronic defects in them. When silicon is doped with electron rich impurities the extra electron becomes delocalized. These delocalized electrons increase the conductivity of doped silicon due to the negatively charged electron, hence silicon doped with electron-rich impurity is called n-type semiconductor while electron-deficit impurities increase the conductivity through positive holes and this type of semiconductors are called /?-type semiconductors.