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Question

How is acetophenone converted to phenol?

A
i) mCPBA, ii) aq. NaOH
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B
i) alk. KMnO4, ii) H3O+
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C
Iodine and NaOH
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D
i) MeMgBr, ii) H2O
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Solution

The correct option is A i) mCPBA, ii) aq. NaOH
a) m-CPBA converts the ketone into an ester which upon alkaline hydrolysis, is reduced to phenol and ethanoate.


b) Treatment of acetophenone with alkaline KMnO4 followed by acidic hydrolysis, yields benzoic acid.

c) Iodoform reaction converts acetophenone to iodoform and sodium benzoate.

d) Grignard reagent reduces acetophenone to 2-phenylpropan-2-ol.

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