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Question

How is Nitric Acid manufactured by Ostwald's Process?

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Solution

Ostwald process to manufacture nitric acid-
Step 1: Catalytic oxidation of Ammonia
A mixture of dry air and dry ammonia in the ratio of 10:1 by volume is compressed and then passed into a platinum gauze which acts as catalyst at about 800.
4NH3+5O24NO+6H2O+Heat
Step 2: Oxidation of nitric oxide
Nitric oxide combines with oxygen to form nitrogen dioxide at about 50°C.
2NO+O22NO2
Step 3: Absorption of nitrogen dioxide in water
The nitrogen dioxide and oxygen present in the air react with water to form nitric acid.
4NO2+2H2O+O24HNO3Nitric acid
Nitric acid obtained is concentrated above 50%. On further distillation, 68% nitric acid is produced.

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