Dear student.
1 molecule of α-ketoglutarate in Kreb's cycle will produce 2 NADH2, 1FADH, 1ATP (Substrate level) = 9 ATP.
2 molecule of α-ketoglutarate in Kreb's cycle will produce = 18 ATP.
NADH2 will be formed in two steps:
During the formation of α-ketoglutarate to Succinyl CoA and from malate to oxaloacetate.
FADH will be formed during the formation of succinate to fumerate.
NADH2 - 3 ATP
FADH- 2 ATP
Regards.