How many Cl atoms can you ionize in the process Cl→Cl++e by the energy liberated for the process Cl+e→Cl− for one Avogadro number of atms. Given IP=13.0eV and EA=3.60eV. Avogadro number =6×1023.
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Solution
Ionization potential is the energy required to remove an electron from the outermost shell of an atom.
∴Cl⟶Cl++e− ; E=13.0eV
Electron affinity is the property of an atom to attract an electron.
∴Cl+e−⟶Cl ;E=−3.6eV
∴ Moles of Cl atoms that can be ionized= 3.6eV13.0eV=0.277 moles