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Question

How many electrons should be added to the reactant to balance the atom whose oxidation number is changing?

Cr2O27Cr+3


  1. 6

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Solution

The correct option is A 6

First multiplyCr+3×2 to balance no of Cr atoms

Cr2O272Cr3+

First let us calculate the oxidation number of the Cr atom on the LHS.

2n-14 = -2 2n =12

n =6

Clearly, the change in oxidation state is 2+6Cr2+3Cr

As you can see, each Cr atom undergoes a change in oxidation of +3 - (+6) = -3. So For each Cr atom 3 electrons must be added to the LHS. So a total of 6 electrons shall be added

Therefore, Cr2O27+6e2Cr3+. Do note that we are not balancing the whole reaction here. This is more like balancing a half reaction.


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