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Question

How many grams of phosphoric acid would be needed to neutralise 100 g of magnesium hydroxide? (The molecular weights of H2PO4=98 and Mg(OH)2=58.3 g/mol respectively)

A
66.7 g
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B
252 g
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C
112 g
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D
168 g
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Solution

The correct option is D 168 g
As the neutralizing reaction between H2PO4 and Mg(OH)2 is as follows:
H2PO4+Mg(OH)2MgPO4+2H2O
this reaction shows that 1 mol of H2PO4 neutralises 1 mol of Mg(OH)2
now to determine the moles of these from given weight of them
moles of Mg(OH)2 = Weight/ molar mass = 100/58.3=1.72 moles
moles of H2PO4 = Weight/ molar mass = x/98 moles ( let wt = x)
so as moles of H2PO4 and Mg(OH)2 must be same., as per balanced equation.
so x/98=1.72
so, x=981.72=168.56 hence nearby 168 g of H2PO4.

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