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Question

How many liters of water has evaporated on concentrating 10 liters of H2SO4 such that its pH decreases from 6 to 5?

A
9
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B
7
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C
5
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D
10
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Solution

The correct option is A 9
Concentration of [H+] a pH 6 : [H+] = antilog (-pH) = antilog (-6) = 1×106M

Concentration of [H+] a pH 5 : [H+] = antilog (-pH) = antilog (-5) = 1×105M

Since the pH 6 is at the initial condition at which the volume was 10 L, then the volume at which the pH is 5 will be:

M1V1=M2V2

1×106M×10L=1×105M×V2

V2=1L

Hence, the volume of water evaporated = 10 - 1 = 9 L

Hence, option A is correct.

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