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Question

How many millilitres of 0.1N H2SO4 solution will be required for complete reaction with a solution containing 0.125g of pure Na2CO3?

A
23.6ml
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B
25.6ml
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C
26.3ml
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D
32.6ml
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Solution

The correct option is B 23.6ml
23.6 mL of 0.1 N H2SO4 solution will be required for complete reaction with a solution containing 0.125 g of pure Na2CO3
For complete reaction no. of equivalents must be equal.
No. of moles of Na2CO3= mass/molar mass =0.125/106=0.001179 mol
No. of equivalents of Na2CO3=no. of moles x valence factor =0.001179×2= 0.002358
This is no. of equivalents H2SO4 must be present for complete reaction.
For H2SO4 no. of equivalents = Normality×volume (in litres)
Therefore volume in L of H2SO4 =0.002358/0.1=0.02358 Litre
=0.02358×1000mil=23.58 ml
So, answer is 23.58 ml be present for complete reaction.

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