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Coordination Complexes

How many mole...

Question

How many moles of $A g C l$ will be precipitated when an excess of $A g N O_{3}$ solution is added to one molar solution of $[C r C l (H_{2} O)_{5}] C l_{2}$ ?

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Solution

Two moles of $A g C l$ will be precipitated when an excess of $A g N O_{3}$ solution is added to one molar solution of $[C r C l (H_{2} O)_{5}] C l_{2}$
$[C r C l (H_{2} O)_{5}] C l_{2} + 2 A g N O_{3} \to [C r C l (H_{2} O)_{5}] (N O_{3})_{2} + 2 A g C l ↓$
Only chloride ions present in ionization sphere will be precipitated. The chlorine present in coordination sphere will not be precipitated.

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