How many moles of KMnO4 are required to oxidise one mole of SnCl2 in acidic medium ?
Equate equivalents.
Equivalents = n−factor×moles
For KMnO4 n-factor is 5. Let moles be 'm'.
So equivalents of KMnO4=5×m=5m.
n-factor for SnCl2 is 2 as it goes from +2−+4 oxidation state. It's moles is 1.
So equivalents is 2.
5m=2
m=25