Energy associated with one mole of photons =N0×h×v
=6.02×1023×6.626×10−34×2.45×109
=97.727×10−2Jmol−1
Energy required to raise the temperature of 225g of water by 75=m×s×t=225×4.18×75=70537.5J
Hence, number of moles of photons required =mstN0hv=70537.597.727×10−2=7.22×104mol.