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Question

How many of the following addition reactions are syn addition reaction?



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Solution

(a) Addition of Br2 in CCl4 goes through anti fashion. On cis alkene, it gives a racemate.

(b) Hydrogenation in presence of Ni catalyst takes place in syn fashion.

(c) Cold basic KMnO4 does syn dihydroxylation of alkene.

(d) Alkynes on reduction with sodium in liquid ammonia form trans alkenes.

(e)Alkynes on reduction with Lindlar’s catalyst give cis alkene.

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