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Question

How many optically active alcohols of molecular formula C6H13O give instant white turbidity with Lucas reagent?

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Solution

No active alcohols of molecular formula C6H13O will give instant white turbidity with Lucas reagent. Lucas reagent is a mixture of anhydrous zinc chloride and HCl. it converts alcohols to alkyl chlorides which results in turbidity. Tertiary alcohols give turbidity immediately, secondary alcohols give turbidity in 3 to 5 minutes and primary alcohols gives turbidity only on heating.

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